Lt. Chadderton et D. Fink, Fullerene genesis by ion beams III. On the absence of latent tracks in GeVion irradiated graphite, RADIAT EFF, 152(2), 2000, pp. 87-107
Irradiation of natural graphite with similar to 1 GeV lead and uranium ions
initiates a phase change to fullerene (C-60) along the particle trajectori
es. High resolution transmission electron microscopy (Dunlop ct al. [II) re
veals no tracks in the bulk in either kinematic or diffraction contrast. Sm
all amoeboid-like surface patches ale formed however, random in distributio
n and proportional in number, but not equivalent to the total ion fluence.
The evidence suggests that molecules of C-60 and other clusters are ejected
from the entry and exit surfaces by electronic sputtering and are then dep
osited.
A mechanism referred to as particle activated prompt anneal (or PAPAf is pr
oposed to explain the absence of latent tracks in the bulk. A reverse cooli
ng and annealing wave permits recovery by epitaxy of the disorder and phase
changes induced by the primary heat wave. Radiation enhanced recovery proc
esses may also play a role. PAPA can additionally explain the absence of in
duced fission fragment tracks in graphite, diamond, silicon and germanium.