Fullerene genesis by ion beams III. On the absence of latent tracks in GeVion irradiated graphite

Citation
Lt. Chadderton et D. Fink, Fullerene genesis by ion beams III. On the absence of latent tracks in GeVion irradiated graphite, RADIAT EFF, 152(2), 2000, pp. 87-107
Citations number
61
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
RADIATION EFFECTS AND DEFECTS IN SOLIDS
ISSN journal
10420150 → ACNP
Volume
152
Issue
2
Year of publication
2000
Pages
87 - 107
Database
ISI
SICI code
1042-0150(2000)152:2<87:FGBIBI>2.0.ZU;2-A
Abstract
Irradiation of natural graphite with similar to 1 GeV lead and uranium ions initiates a phase change to fullerene (C-60) along the particle trajectori es. High resolution transmission electron microscopy (Dunlop ct al. [II) re veals no tracks in the bulk in either kinematic or diffraction contrast. Sm all amoeboid-like surface patches ale formed however, random in distributio n and proportional in number, but not equivalent to the total ion fluence. The evidence suggests that molecules of C-60 and other clusters are ejected from the entry and exit surfaces by electronic sputtering and are then dep osited. A mechanism referred to as particle activated prompt anneal (or PAPAf is pr oposed to explain the absence of latent tracks in the bulk. A reverse cooli ng and annealing wave permits recovery by epitaxy of the disorder and phase changes induced by the primary heat wave. Radiation enhanced recovery proc esses may also play a role. PAPA can additionally explain the absence of in duced fission fragment tracks in graphite, diamond, silicon and germanium.