Besides the investigation of the emission band, accurate measurements of bo
th lifetime and quantum yield were performed concerning Cu+ and Ag+ lumines
cence in alkali halides. The validity of the Pedrini model for the decay pr
ocess was verified and was then extended to include the off-centre configur
ation; evidence of non-radiative processes tin NaCl : Ag+) as well as of a
switching for on and off-centre configurations in NaCl:Cu+ was ascertained.
The first data concerning the emission of Au+ in KCl were obtained.