KO2/crown ether: a novel catalytic system for the hydrosilation and Tishchenko reaction of aromatic aldehydes

Authors
Le Bideau, F Coradin, T Gourier, D Henique, J Samuel, E
Citation
F. Le Bideau et al., KO2/crown ether: a novel catalytic system for the hydrosilation and Tishchenko reaction of aromatic aldehydes, TETRAHEDR L, 41(27), 2000, pp. 5215-5218
Citations number
8
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
27
Year of publication
2000
Pages
5215 - 5218
Database
ISI
SICI code
0040-4039(20000701)41:27<5215:KEANCS>2.0.ZU;2-1
Abstract
A new catalytic system KO2/18-crown-6 ether is reported to lead, in the pre sence of Et3SiH, to hydrosilation and Tishchenko reaction of aromatic aldeh ydes. The nature of the products obtained are shown to depend on aldehydes and experimental conditions. (C) 2000 Elsevier Science Ltd. All rights rese rved.