Insertion of metallated epoxides into zirconacycles

Authors
Kasatkin, AN Whitby, RJ
Citation
An. Kasatkin et Rj. Whitby, Insertion of metallated epoxides into zirconacycles, TETRAHEDR L, 41(27), 2000, pp. 5275-5280
Citations number
39
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
27
Year of publication
2000
Pages
5275 - 5280
Database
ISI
SICI code
0040-4039(20000701)41:27<5275:IOMEIZ>2.0.ZU;2-H
Abstract
Metallated epoxides (epoxysilanes, epoxynitriles, epoxystyrene) insert effi ciently into zirconacycles via a 1,2-metallate rearrangement to form interm ediates which eliminate Cp2Zr(R)O- to afford substituted alkenes. (C) 2000 Elsevier Science Ltd. All rights reserved.