The NARC-based approach to the enantioselective synthesis of the zaragozicacids. Synthesis of a C 5-alkoxycarbonyl-substituted 2,8-dioxabicyclo[3.2.1]octane

Authors
Perlmutter, P Selajarern, W
Citation
P. Perlmutter et W. Selajarern, The NARC-based approach to the enantioselective synthesis of the zaragozicacids. Synthesis of a C 5-alkoxycarbonyl-substituted 2,8-dioxabicyclo[3.2.1]octane, AUST J CHEM, 53(4), 2000, pp. 349-353
Citations number
46
Categorie Soggetti
Chemistry
Journal title
AUSTRALIAN JOURNAL OF CHEMISTRY
ISSN journal
00049425 → ACNP
Volume
53
Issue
4
Year of publication
2000
Pages
349 - 353
Database
ISI
SICI code
0004-9425(2000)53:4<349:TNATTE>2.0.ZU;2-U
Abstract
A direct method for the preparation of C5-alkoxycarbonyl-substituted 2,8-di oxabicyclo[3.2.1]octanes is described. The key process involves a highly st ereoselective (NARC) sequence of a nucleophilic addition followed by ring c losure.