Synthesis of a stable stibabismuthene; the first compound with an antimony-bismuth double bond

Citation
T. Sasamori et al., Synthesis of a stable stibabismuthene; the first compound with an antimony-bismuth double bond, CHEM COMMUN, (15), 2000, pp. 1353-1354
Citations number
19
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
15
Year of publication
2000
Pages
1353 - 1354
Database
ISI
SICI code
1359-7345(2000):15<1353:SOASST>2.0.ZU;2-#
Abstract
The condensation reaction of an overcrowded dihydrostibine with dibromobism uthine using 1,8-diazabicyclo[5.4.0]undec-7-ene as a base afforded the firs t stable stibabismuthene, the formation of which was evidenced by UV-VIS an d Raman spectra and its chemical reactivity.