Oxygen initiated unprecedented condensation of propargylamine into the 1,3-di(propargylimino)propylateanion coordinated to cobalt(III)

Authors
Sidorov, AA Ponina, MO Deomidov, SM Novotortsev, VM Demonceau, A Nefedov, SE Eremenko, IL Moiseev, II
Citation
Aa. Sidorov et al., Oxygen initiated unprecedented condensation of propargylamine into the 1,3-di(propargylimino)propylateanion coordinated to cobalt(III), CHEM COMMUN, (15), 2000, pp. 1383-1384
Citations number
4
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
15
Year of publication
2000
Pages
1383 - 1384
Database
ISI
SICI code
1359-7345(2000):15<1383:OIUCOP>2.0.ZU;2-J
Abstract
Condensation of coordinated propargylamine into the unprecedented 1,3-di(pr opargylimino)propylateanion, an analogue of the acetylacetonate anion, is i nitiated by dioxygen in the Co(ii) polymeric trimethylacetate complex/NH2CH 2C=CH system; molecular structures of the intermediate complex, Co(O2CCMe3) (2)(H2NCH2C=CH)(4) and final product Co(O2CCMe3)(2)(NH2CH2C=CH)(2)[N,N'-(HC =CCH2NCHCHCHNCH2C=CH)] were established by X-ray analysis.