Chalcogen atom transfer reactions. Kinetics of terminal bonded sulfur atomtransfer between main group metal centers

Authors
Foley, SR Richeson, DS
Citation
Sr. Foley et Ds. Richeson, Chalcogen atom transfer reactions. Kinetics of terminal bonded sulfur atomtransfer between main group metal centers, CHEM COMMUN, (15), 2000, pp. 1391-1392
Citations number
21
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
15
Year of publication
2000
Pages
1391 - 1392
Database
ISI
SICI code
1359-7345(2000):15<1391:CATRKO>2.0.ZU;2-H
Abstract
The first comprehensive investigation of S atom transfer between two differ ent metal centers is presented using the reaction of the terminal chalcogen atom bearing complex [CyNC(Bu-t)NCy](2)SnS with [CyNC(Bu-t)NCy](2)Ge-II; t his multielectron redox reaction between Ge-II and Sn-IV proceeds via a sec ond-order process with an inner sphere mechanism involving a mu-S intermedi ate as the proposed pathway; results of S and Se atom transfer between [CyN C(Bu-t)NCy](2)Ge and PPh3 are also presented.