Side chain elongation causes a change from enthalpy driven to entropy driven binding in the molecular recognition of tetraanionic peptides

Authors
Salvatella, X Peczuh, MW Gairi, M Jain, RK Sanchez-Quesada, J de Mendoza, J Hamilton, AD Giralt, E
Citation
X. Salvatella et al., Side chain elongation causes a change from enthalpy driven to entropy driven binding in the molecular recognition of tetraanionic peptides, CHEM COMMUN, (15), 2000, pp. 1399-1400
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
15
Year of publication
2000
Pages
1399 - 1400
Database
ISI
SICI code
1359-7345(2000):15<1399:SCECAC>2.0.ZU;2-J
Abstract
In binding to tetraguanidinium compounds, the average side chain length of tetraanionic peptides determines the thermodynamics of binding, the degree of helix induction and the rigidity of the complex formed.