A simple and efficient methodology has been established for the selective s
ynthesis of anatase and rutile as well as their mixtures with various precu
rsors using ultrasound irradiation; the products, the particle sizes of whi
ch are nanometric (< 9 nm), are dependent both upon the reaction temperatur
e and the precursor used; a substantial reduction in reaction time as well
as reaction temperature is observed as compared to the corresponding hydrot
hemal processes.