Synthesis and structure of [((BuN)-N-t)P(mu-NBut)(2)P(PCy)Li-2 center dot thf](2); an unusual cage compound containing an amido/phosphido functionalised [((BuN)-N-t)P(mu-NBut)(2)P(PCy)](2-) dianion (Cy = C6H11)

Authors
Bashall, A Elvidge, BR Beswick, MA Kidd, SJ McPartlin, M Wright, DS
Citation
A. Bashall et al., Synthesis and structure of [((BuN)-N-t)P(mu-NBut)(2)P(PCy)Li-2 center dot thf](2); an unusual cage compound containing an amido/phosphido functionalised [((BuN)-N-t)P(mu-NBut)(2)P(PCy)](2-) dianion (Cy = C6H11), CHEM COMMUN, (15), 2000, pp. 1439-1440
Citations number
22
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
15
Year of publication
2000
Pages
1439 - 1440
Database
ISI
SICI code
1359-7345(2000):15<1439:SASO[C>2.0.ZU;2-2
Abstract
The reaction of [((BuNH)-N-t)P(mu-NBut)(2)PCl] (1) with CyPHLi and (BuLi)-L i-n in toluene gives [((BuN)-N-t)P(mu-NBut)(2)P(PCy)Li-2. thf](2) (2), an u nusual aggregate containing the first example of a phosphine-functionalised cyclodiphosphazane anion [((BuN)-N-t)P(mu-NBut)(2)P(PCy)](2-).