Flammability properties of polymer - Layered-silicate nanocomposites. Polypropylene and polystyrene nanocomposites

Citation
Jw. Gilman et al., Flammability properties of polymer - Layered-silicate nanocomposites. Polypropylene and polystyrene nanocomposites, CHEM MATER, 12(7), 2000, pp. 1866-1873
Citations number
31
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
CHEMISTRY OF MATERIALS
ISSN journal
08974756 → ACNP
Volume
12
Issue
7
Year of publication
2000
Pages
1866 - 1873
Database
ISI
SICI code
0897-4756(200007)12:7<1866:FPOP-L>2.0.ZU;2-G
Abstract
Our continuing study of the mechanism of flammability reduction of polymer- layered-silicate nanocomposites has yielded results for polypropylene-graft -maleic anhydride and polystyrene-layered-silicate nanocomposites using mon tmorillonite and fluorohectorite. Cone calorimetry was used to measure the heat release rate and other flammability properties of the nanocomposites, under well-controlled combustion conditions. Both the polymer-layered-silic ate nanocomposites and the combustion residues were studied by transmission electron microscopy and X-ray diffraction. We have found evidence for a co mmon mechanism of flammability reduction. We also found that the type of la yered silicate, nanodispersion, and processing degradation have an influenc e on the flammability reduction.