Synthesis of C-2 oxygenated compounds from syngas in supercritical cyclohexane

Citation
Xz. Wang et al., Synthesis of C-2 oxygenated compounds from syngas in supercritical cyclohexane, CHIN J CHEM, 18(4), 2000, pp. 635-637
Citations number
10
Categorie Soggetti
Chemistry
Journal title
CHINESE JOURNAL OF CHEMISTRY
ISSN journal
1001604X → ACNP
Volume
18
Issue
4
Year of publication
2000
Pages
635 - 637
Database
ISI
SICI code
1001-604X(200007/08)18:4<635:SOCOCF>2.0.ZU;2-C
Abstract
Catalytic synthesis of C-2 oxygenated compounds from syngas in supercritica l cyclohexane was reported in this paper. The effect of the molar ratio of media to feed on the conversion and selectivity was mainly discussed. The r esults showed that the selectivity of C-2 oxygenated compounds in supercrit ical cyclohexane was greatly improved, and the by-products of acetic acid,a cetic eater and alkanes were efficiently suppressed. Although the CO conver sion was slightly declined, the spacetime yield of C-2 oxygenated compounds basically kept the constant at high media/feed ratio.