The thermally stimulated shape memory behavior of ethylene oxide-butylene t
erephthalate (EOBT) segmented copolymers with different soft segment molecu
lar weight and hard segment content was investigated. The deformation recov
ery ratio R-f of the EOBT samples increases with the soft segment molecular
weight and the hard segment weight content, while the average overall defo
rmation recovery speed V-r increases with the hard segment content. The tem
perature of maximum deformation recovery speed (T-M) is determined by the m
elting temperature of the soft segment crystals and the stability of the cr
ystallized hard segment domains.