J. Stejskal et al., Polyaniline dispersions 10. Coloured microparticles of variable density prepared using stabilizer mixtures, COLLOID P S, 278(7), 2000, pp. 654-658
Green polyaniline microparticles of variable density were prepared by the d
ispersion polymerization of aniline in the presence of a mixture of steric
stabilizers. A water-soluble polymer stabilizer, polyacrylamide, and a part
iculate one, colloidal silica, were jointly used for this purpose. Silica w
as preferentially incorporated into the dispersion particles. The size of t
he particles was determined by dynamic light scattering. The colour of the
polyaniline colloids was characterized by the absorption spectra. The densi
ty of the particles increased with increasing silica content, while the con
ductivity of the composites prepared from dispersions was reduced at the sa
me time.