Aa. Gutkin et al., MECHANISM FOR THE LOW-TEMPERATURE ALIGNMENT OF DISTORTIONS OF THE VGATEAS COMPLEXES IN N-TYPE GAAS UNDER UNIAXIAL PRESSURE, Zeitschrift für physikalische Chemie, 200, 1997, pp. 217-224
Citations number
15
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
The polarization of the 1.18 eV photoluminescence band associated with
the VGaTeAs complexes in n-GaAs was studied under polarized resonant
excitation at various temperatures and uniaxial pressures. An analysis
was made within a model of an initially trigonal complex which in the
light-emitting state is subject to the Jahn-Teller distortion retaini
ng the symmetry plane of the {110}-type. It is shown that i) the groun
d state of the complex is also subject to the distortion; ii) at tempe
ratures below 130 K the processes of reorientation and alignment occur
in the ground state and the distortion orientation is conserved at th
e subsequent transition to the light-emitting state.