Design equations for optimized PEM fuel cell electrodes

Citation
Cc. Boyer et al., Design equations for optimized PEM fuel cell electrodes, J APPL ELEC, 30(7), 2000, pp. 777-786
Citations number
38
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF APPLIED ELECTROCHEMISTRY
ISSN journal
0021891X → ACNP
Volume
30
Issue
7
Year of publication
2000
Pages
777 - 786
Database
ISI
SICI code
0021-891X(200007)30:7<777:DEFOPF>2.0.ZU;2-1
Abstract
This paper presents simple mathematical expressions that can be used for op timizing fuel cell electrode structures, specifically polymer electrolyte m embrane fuel cells (PEMFCs). Based on the effectiveness factor, equations r elate current density to catalyst utilization and a mass transfer coefficie nt. These can be used to screen new materials or identify which specific pr ocesses need to be improved in an existing electrode design. The optimum th ickness, or catalyst loading, and maximum current that can be achieved with a given set of materials can be calculated from a simple set of equations based on the mass transfer characteristics of the electrode materials. Thes e methods can save considerable experimental time and cost during electrode development.