The modification of the rate or formation of interpenetrant simultaneous in
organic-organic (SIPIN) networks of poly(vinyl acetate) (PVAc)-SiO2 was stu
died. The P(VAc) network was formed by radical polymerization with benzoyl
peroxide in the presence of a crosslinked monomer, diethylen glycol bis mal
eate. SiO2 network was obtained by sol-gel reaction of tetraethoxysilane (T
EOS) catalyzed by radical polymerizable acids: maleic acid (MA) and acrylic
acid (AA). The reaction medium was the ethylic alcohol-water mixture. The
formation rate of SIPIN depends on the ratio of initial organic over aqueou
s phases in case of catalysis by MA. The gelling times for MA are higher th
an those for AA. This behavior inversely proportional to the acid strength
is assigned to the selective interaction of the acids with the hydrocarbona
ted or aqueous zone of initial systems. Crotonic acid (CrA) is partitioned
in the hydrocarbonate zone where TEOS also lies. The glass transition tempe
rature of organic network, P(VAc), increases with the increase of crosslink
ing agent concentration. It is higher in the network prepared in presence o
f MA owing to the higher number of hydrogen bonds induced by COOH.