The essential oils obtained from air-dried subterranean parts of Valeriana
officinalis ssp. collina (Wallr.) Nyman (Valerianaceae), 'Shipka,' was anal
yzed by GC and GC/MS, and 62 components were identified. The oil yield, col
lected in plants grown in 1995 and 1938, was 0.42% (v/m) and 0.40% (v/m) re
spectively, related to the air-dried roots. Two new sesquiterpenes, (-)-pac
ifigorgia-1(6),10-diene and (-)-valerena-4,7(11)-diene were identified for
the first rime in both oils. Some major constituents were bornyl acetate (6
.0%-7.3%), spathulenol (5.2%-4.1%), valeranone (12.0%-6.8%), valerenal (9.1
%-8.5%), alpha-kessyl acetate (2.1%-6.2%) and (-)-vaierena-4,7(11)-diene (7
.2%-4.6%).