A model analysis of the tropical South Atlantic Ocean tropospheric ozone maximum: The interaction of transport and chemistry

The meteorological and photochemical nature of the South Atlantic Ocean tro pospheric column ozone maximum is examined by analyzing the Geophysical Flu id Dynamics Laboratory (GFDL) Global Chemical Transport Model (GCTM) simula tion during the Southern Hemisphere late winter. An ozone maximum of greate r than 40 Dobson units is produced by the GCTM over the South Atlantic Ocea n. The model is evaluated against available meteorological and ozone data a nd found to be in good qualitative agreement with observed wind fields, sat ellite measurements of tropospheric column ozone, tropospheric column ozone produced from ozonesonde data, and vertical profiles from ozonesondes. A q uantitative analysis is performed over an area of the South Atlantic Ocean essentially devoid of local NOx sources and for a time, September, when the regional tropospheric ozone mass is at a maximum. The tropospheric mass of reactive nitrogen transported into the region is a result of source contri butions from lightning (49%), biomass burning (36%), and 15% from the remai ning NOx sources (fossil fuel plus biogenic plus stratosphere plus aircraft ). Even with the removal of biomass burning NOx from the ozone photochemica l system, the GCTM still produces an oceanic tropospheric column ozone maxi mum, suggesting the ozone phenomenon existed before agricultural burning by humans. The structure of clean air CO/CH4 net chemistry consists of ozone production in the upper troposphere (+2.2 Tg/month), weak destruction in th e middle troposphere (-1.8 Tg/month), and strong destruction in the lower t roposphere (-4.2 Tg/month). Through photochemistry, the two largest NOx sou rces help control the vertical profile of ozone with lightning dominating i n the upper troposphere, while the relative importance of biomass burning i s virtually constant throughout the troposphere. A mass budget analysis of ozone over the tropospheric South Atlantic Ocean reveals that net mass tran sport of ozone into the domain is nearly balanced by net chemical destructi on and deposition and that the mass transport into and out of the region ar e comparable to the chemical production and destruction terms. The three-di mensional circulation governing the ozone vertical structure is one of hori zontal mass convergence and net chemical production supplying ozone to the upper troposphere which is fluxed downward by subsidence and removed in the boundary layer by net chemical destruction, deposition, and horizontal mas s divergence.