Bridged aminotroponiminate complexes of lutetium

Authors
Roesky, PW
Citation
Pw. Roesky, Bridged aminotroponiminate complexes of lutetium, J ORGMET CH, 603(2), 2000, pp. 161-166
Citations number
59
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
603
Issue
2
Year of publication
2000
Pages
161 - 166
Database
ISI
SICI code
0022-328X(20000529)603:2<161:BACOL>2.0.ZU;2-M
Abstract
The reaction of the salt di-potassium-1,3-di(2-(isopropylamino)troponiminat e)-propane, K-2[(Pr-i)TP], with lutetium trichloride leads to [[(Pr-i)TP]Lu Cl](2) (1). 1 was characterized by single crystal X-ray crystallography. To study the reactivity of 1 some selected derivatives such as alkyl, amide, eta(5)-cyclopentadienyl, and eta(3)-borohydride complexes were synthesized by substitution of the chlorine atom of 1. (C) 2000 Published by Elsevier S cience S.A. All rights reserved.