This paper provides a review of synthesis of the phthalocyanines containing
various macrocycles at the peripheral position of the benzene rings. They
are expected to be suitable to change the chemical and physical properties
toward the need of technologycal applications. In addition, transition and
alkali metal phthalocyanine complexes especially rare-earth bis phthalocyan
ines, are object of intense investigations for their unique optical and ele
ctrochemical properties. The methodology of synthesis, purification and yie
ld varies the structural designation which is restricted and depends on the
starting compounds. Copyright (C) 2000 John Wiley & Sons, Ltd.