Sol-gel processing of tellurium oxide and suboxide thin films with potential for optical data storage application

A novel sol-gel processing route has been developed for the production of t ellurium oxide (TeO2) and tellurium suboxide (TeOx) thin films. The process has been used to deposit thin films on glass substrates by the dip coating process. These films have been shown to undergo thermally induced, reversi ble changes in optical properties on heating at appropriate temperatures. F ormation of TeOx was found to occur at low temperatures by direct breakdown of the sol-gel derived material even in the absence of reducing agents whi lst the principal optical effects corresponded to the formation of TeOx and alpha-TeO2 at temperatures of < 200 degrees C and < 450 degrees C respecti vely. The relatively low temperatures required to induce significant optica l effects are comparable with conventionally prepared TeOx and offer the po tential application of these materials in optical data storage systems.