Hw. Wang et al., Enhancement of the instantaneous mass-transfer coefficient in large diameter pipeline under water/oil flow, J ELCHEM SO, 147(7), 2000, pp. 2552-2555
A mass-transfer study was carried out in water and water/oil flow in a larg
e diameter flow loop by a limiting current density technique using oxidatio
n of Fe(CN)(6)(4-) in 1 hi NaOH. High-frequency and high-magnitude mass-tra
nsfer coefficients were found by potentiostatic measurements and may accoun
t for the corrosion rate enhancement in water/oil flow. The effect of oil d
roplets on the mass-transfer enhancement is highlighted and a mechanism of
mass-transfer coefficient oscillation is proposed. (C) 2000 The Electrochem
ical Society. S0013-4651(99)09-089-8. All rights reserved.