Adequate die-to-lead frame adhesion is necessary for lead-on-chip (LOC) pac
kage integrity during and after the manufacturing process. Inadequate adhes
ion may result in a variety of defects such as die adhesion failure, margin
al wire bond, broken wire, and bent leads, which ultimately lead to electri
cal failure [Mallik, US Patent No. 4,835,120 (May 1989); M. Amagai and E. K
awasaki, Mater. Res. Symp. Proc. 338, 185 (1994)]. Adhesion between the LOC
tape and the polyimide passivation is affected by the surface properties o
f both materials. Understanding the relationships between these properties
helps engineers eliminate inadequate adhesion at die attach and continuousl
y improve the manufacturing process. To this end, die that exhibit inadequa
te adhesion at die attach are analyzed and compared with die that exhibit a
dequate adhesion characteristics. To focus on the surface chemistry and phy
sical properties of the passivation layer, x-ray photoelectron spectroscopy
, Fourier-transform infrared spectroscopy, atomic force microscopy (AFM), a
nd surface energy are used. Molecular concentrations and orientations are i
nvestigated and related to inadequate adhesion at die attach. (C) 2000 Amer
ican Vacuum Society. [S0734-2101(00)12104-9].