We report a breakthrough for selective etching of GaAs over AlxGa1-xAs, x=0
.2, layer with a high density plasma source. This result is particularly im
portant for III-V devices such as heterojunction bipolar transistors (HBTs)
or high electron mobility transistors (HEMTs). For example, fabrication of
HBTs requires a process for selective etching of a GaAs contact layer whil
e stopping on AlGaBs layer. Inductively coupled plasma (ICP) etching with B
Cl3/SF6/N-2/He chemistries showed extremely high selectivity of GaAs over A
lGaAs (>200:1) and a photoresist (>10:1). This process also produced excell
ent sidewall passivation on GaAs with reasonably high rate (>1500 Angstrom
/min.). Both scanning electron microscope and atomic force microscope data
showed AlGaAs etch stop layer was quite smooth after processing. We found t
hat He played a key role in enhancing selectivity and obtaining smooth AlGa
As surfaces. When used with resist masks, addition of N-2 into BCl3/SF6 pla
sma helped formation of passivation on the sidewall and maintained high ani
sotropy. An optimized condition with BCl3/SF6/N-2/He ICP plasmas showed exc
ellent pattern transfer into GaAs with high rate, anisotropy, and selectivi
ty. (C) 2000 American Vacuum Society. [S0734-2101(00)05804-8].