The role of peroxo complexes in the catalytic decomposition of H2O2 in thepresence of Cu(II) hydroxides

Authors
Elizarova, GL Matvienko, LG Ogorodnikova, OL Parmon, VN
Citation
Gl. Elizarova et al., The role of peroxo complexes in the catalytic decomposition of H2O2 in thepresence of Cu(II) hydroxides, KINET CATAL, 41(3), 2000, pp. 332-339
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
KINETICS AND CATALYSIS
ISSN journal
00231584 → ACNP
Volume
41
Issue
3
Year of publication
2000
Pages
332 - 339
Database
ISI
SICI code
0023-1584(200005/06)41:3<332:TROPCI>2.0.ZU;2-M
Abstract
The catalytic decomposition of hydrogen peroxide is studied in the presence of colloidal and silicagel-supported Cu(OH)(2). Copper peroxo complexes wi th different activities were identified. The reaction is molecular without radical formation. The mechanisms of H2O2 decomposition are discussed.