Kinetics of soot formation in tetrachloromethane pyrolysis

Authors
Zhil'tsova, IV Zaslonko, IS Karasevich, YK Wagner, HG
Citation
Iv. Zhil'Tsova et al., Kinetics of soot formation in tetrachloromethane pyrolysis, KINET CATAL, 41(3), 2000, pp. 366-376
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
KINETICS AND CATALYSIS
ISSN journal
00231584 → ACNP
Volume
41
Issue
3
Year of publication
2000
Pages
366 - 376
Database
ISI
SICI code
0023-1584(200005/06)41:3<366:KOSFIT>2.0.ZU;2-E
Abstract
Kinetics of soot formation is studied in tetrachloromethane pyrolysis behin d shock waves. The time dependences of macrokinetic characteristics of soot particle growth (the induction period, the soot yield, and the apparent ra te constant of soot particle growth) are determined. Based on the experimen tal data, the quantitative model of soot formation is developed for tetrach loromethane pyrolysis behind shock waves. Special attention is paid to the thermal effects in CCl4 pyrolysis.