Lipase-catalyzed regio- and stereoselective acylation of hydroxy groups insteroid side chains

Authors
Santaniello, E Ferraboschi, P Reza-Elahi, S
Citation
E. Santaniello et al., Lipase-catalyzed regio- and stereoselective acylation of hydroxy groups insteroid side chains, MONATS CHEM, 131(6), 2000, pp. 617-622
Citations number
20
Categorie Soggetti
Chemistry
Journal title
MONATSHEFTE FUR CHEMIE
ISSN journal
00269247 → ACNP
Volume
131
Issue
6
Year of publication
2000
Pages
617 - 622
Database
ISI
SICI code
0026-9247(200006)131:6<617:LRASAO>2.0.ZU;2-P
Abstract
Lipase from Pseudomonas cepacia (PCL) catalyzes the regio- and stereoselect ive acylation of primary and secondary hydroxy groups in steroid side chain s under irreversible transesterification conditions with vinyl acetate in o rganic solvents.