Oscillatory clusters are sets of domains in which nearly all elements in a
given domain oscillate with the same amplitude and phase(1-4). They play an
important role in understanding coupled neuron systems(5-8). In the simple
st case, a system consists of two clusters that oscillate in antiphase and
can each occupy multiple fixed spatial domains. Examples of cluster behavio
ur in extended chemical systems are rare, but have been shown to resemble s
tanding waves(9-13), except that they lack a characteristic wavelength. Her
e we report the observation of so-called 'localized clusters'-periodic anti
phase oscillations in one part of the medium, while the remainder appears u
niform-in the Belousov-Zhabotinsky reaction-diffusion system with photochem
ical global feedback. We also observe standing clusters with fixed spatial
domains that oscillate periodically in time and occupy the entire medium, a
nd irregular clusters with no periodicity in either space or time, with sta
nding clusters transforming into irregular clusters and then into localized
clusters as the strength of the global negative feedback is gradually incr
eased. By incorporating the effects of global feedback into a model of the
reaction, we are able to simulate successfully the experimental data.