We have investigated double electron capture with simultaneous target ioniz
ation in collisions of 25-keV/amu He-3(2+) projectiles on argon. Doubly dif
ferential cross sections for electrons emitted in angles 0 degrees, 20 degr
ees, 45 degrees, 90 degrees, 128 degrees, 175 degrees, in coincidence with
the neutralized projectiles were obtained. To establish the relative import
ance of the double capture channel in the electron emission at the present
intermediate impact velocity, differential cross sections for total electro
n emission were also measured. A narrow symmetric cusp-shaped structure for
electrons with velocity close to the ion velocity, associated with the neu
tral emerging projectile, is observed. Binary encounter electrons, masked b
y other processes in total emission, are clearly observed for the double ca
pture plus ionization channel.