We show that an arbitrary system described by two dipole moments exhibits c
oherent superpositions of internal states that can be completely decoupled
fi om the dissipative interactions (responsible for decoherence) and an ext
ernal driving laser field. These superpositions, known as dark or trapping
states, can he completely stable or can coherently interact with the remain
ing states. We examine the master equation describing the dissipative evolu
tion of the system and identify conditions for population trapping and also
classify processes that can transfer the population to these undriven and
nondecaying states. It is shown that coherent transfers are possible only i
f the two systems are nonidentical, that is the transitions have different
frequencies and/or decay rates. in particular, we find that the trapping co
nditions can involve both coherent and dissipative interactions, and depend
ing on the energy level structure of the system, the population can be trap
ped in a linear superposition of two or more bare states, a dressed state c
orresponding to an eigenstate of the system plus external fields or, in som
e cases. in one of the excited states of the system. A comprehensive analys
is is presented of the different processes that are responsible for populat
ion trapping, and we illustrate these ideas with three examples of two coup
led systems: single V- and Lambda-type three-level atoms and two nonidentic
al tao-level atoms, which are known to exhibit dark states. We show that th
e effect of population trapping does not necessarily require decoupling of
the antisymmetric superposition from the dissipative interactions. We also
find that the vacuum-induced coherent coupling between the systems could be
easily observed in Lambda-type atoms. Our analysis of the population trapp
ing in two nonidentical atoms shows that the atoms can be driven into a max
imally entangled state which is completely decoupled from the dissipative i
nteraction.