We study thermodynamic behaviors of the antiferromagnetic zigzag spill chai
n in magnetic fields, using the density-matrix renormalization-group method
for the quantum transfer matrix. We focus on the thermodynamics of the sys
tem near the critical fields in the ground-state magnetization process (M-H
curve): the saturation field, the lower critical field associated with exc
itation gap, and the field at the middle-field cusp singularity. We calcula
te magnetization. susceptibility, and specific heat of the zigzag chain in
magnetic fields at finite temperatures. and then discuss how the calculated
quantities reflect the low-lying excitations of the system related with th
e critical behaviors in the M-H curve.