Kinetic simulation of plasmas in which equilibrium occurs over ion time sca
les poses a computational challenge due to disparity with electron time sca
les. Hybrid electrostatic particle-in-cell (PIC) algorithms are presented i
n which most of the electrons reach thermodynamic equilibrium [Maxwell-Bolt
zmann (MB) distribution function] each time step. Conservation of charge en
ables convergence of the nonlinear Poisson equation. Energy conservation is
used to determine the temperature of the Boltzmann species. This article f
irst develops an algorithm where all the electrons have a MB energy distrib
ution, either with a full MB distribution or with a truncation of the high
energy tail. Second, high energy PIC electrons are added to the truncated d
istribution so that high energy electrons are modeled kinetically by PIC an
d low energy electrons (the majority) are modeled by the MB distribution. C
ollisions for PIC electrons are included via a Monte Carlo model, while for
the MB electrons, the distributions are integrated with energy dependent c
ross sections. The MB model is not constrained by the electron time scale w
hich decreases the required computer time by about the square root of the m
ass ratio of ion to electron. However, the hybrid boundary conditions are m
ore complex and the simulation is not quite self-consistent. Comparison bet
ween full PIC and the PIC-MB hybrid is made for simulations of photo-ionize
d sustained discharges and current-driven dc discharges. (C) 2000 American
Institute of Physics. [S1070-664X(00)03408-X].