The design of functionalized silicone polymers for chemical sensor detection of nitroaromatic compounds

The solubility properties of a series of nitroaromatic compounds have been determined and utilized with known linear solvation energy relationships to calculate their sorption properties in a series of chemoselective polymers . These measurements and results were used to design a series of novel chem oselective polymers to target polynitroaromatic compounds. The polymers hav e been evaluated as thin sorbent coatings on surface acoustic wave (SAW) de vices for their vapor sorption and selectivity properties. The most promisi ng materials tested, include siloxane polymers functionalized with acidic p endant groups that are complimentary in their solubility properties for nit roaromatic compounds. The most sensitive of the new polymers exhibit SAW se nsor detection limits for nitrobenzene (NB) and 2, 4-dinitrotoluene in the low parts per billion (ppb) and low parts per trillion (ppt) concentration range, respectively. Polymers with favorable physicochemical properties exh ibit low water vapor sorption, and rapid signal kinetics for NE, reaching 9 0% of signal response in 4 s. Studies with an in situ infrared spectroscopy technique are used to determine the mechanism of interaction between nitro aromatic compounds and the chemoselective polymer. (C) 2000 Elsevier Scienc e S.A. All rights reserved.