Composite films of tetraphenylporphyrin embedded in various of polymer matr
ix were prepared and their optical responses to hydrogen chloride (HCl) gas
were examined. The absorbance of the Soret- and Q-bands for free-base tetr
atphenylporphyrin is reversibly sensitive to parts per million (ppm) levels
of HCl. The lower T-g of polymer matrix than the sensing temperature is ef
fective to enhance the sensitivity of the Soret- and Q-band region. (C) 200
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