Spirocyclopropanated benzoazocinones and tetrahydropyridones from bicyclopropylidene by 1,3-dipolar cycloaddition/Rearrangement

Authors
Cordero, FM Barile, I Brandi, A Kozhushkov, SI de Meijere, A
Citation
Fm. Cordero et al., Spirocyclopropanated benzoazocinones and tetrahydropyridones from bicyclopropylidene by 1,3-dipolar cycloaddition/Rearrangement, SYNLETT, (7), 2000, pp. 1034-1036
Citations number
11
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
7
Year of publication
2000
Pages
1034 - 1036
Database
ISI
SICI code
0936-5214(200007):7<1034:SBATFB>2.0.ZU;2-I
Abstract
1,3-Dipolar cycloaddition of N-aryl-C-phenylnitrones to bicyclopropylidene and subsequent thermal rearrangement afforded mixtures of spirocyclopropane -annelated tetrahydropyridones 12 and benzoazocinones 13 in good overall is olated yields (61-82%). The effect of para-substituents on the N-aryl ring has been found to be marginal.