PARTIAL REGENERATION OF AN AGED COMMERCIAL AUTOMOTIVE CATALYST

Citation
Tn. Angelidis et Vg. Papadakis, PARTIAL REGENERATION OF AN AGED COMMERCIAL AUTOMOTIVE CATALYST, Applied catalysis. B, Environmental, 12(2-3), 1997, pp. 193-206
Citations number
23
Categorie Soggetti
Chemistry Physical","Engineering, Environmental
ISSN journal
09263373
Volume
12
Issue
2-3
Year of publication
1997
Pages
193 - 206
Database
ISI
SICI code
0926-3373(1997)12:2-3<193:PROAAC>2.0.ZU;2-D
Abstract
An aged commercial three-way automotive catalyst was examined with res pect to regeneration procedures. Catalyst samples were leached with ac etic acid to remove contaminants accumulated on the catalyst surface d uring operation. The optimum leaching conditions concerning acetic aci d concentration, solution feed rate and temperature were investigated. The leached samples were examined for their catalytic activity (CO an d C2H4 oxidation, NO reduction and N-2 production) in comparison with samples of fresh and aged catalysts. The leaching procedure improves c onsiderably the catalytic activity, where in the case of C2H4 oxidatio n, NO reduction reaches the activity of the fresh catalyst.