Frequency-modulation spectroscopy with blue diode lasers

Frequency-modulation spectroscopy provides ultrasensitive absorption measur ements. The technique is especially adaptable to diode lasers, which can be modulated easily, and has been used extensively in the near-infrared and i nfrared spectral regions. The availability of blue diode lasers now means t hat the accessible wavelength region can be increased. We successfully demo nstrate wavelength-modulation spectroscopy and two-tone frequency-modulatio n spectroscopy for the weak second resonance line of potassium at 404.8 nm and for the transition at 405.8 nm in lead, starting from the thermally pop ulated 6p(2) P-3(2) metastable level, information on the modulation paramet ers is obtained with a fitting procedure. Experimental signal-to-noise rati os: at different absorption levels are compared with theoretical signal-to- noise ratios and show good agreement. Detection sensitivities of 2 x 10(-6) and 5 x 10(-6) for wavelength and two-tone frequency-modulation spectrosco py, respectively, for a 120-Hz bandwidth are demonstrated. (C) 2000 Optical Society of America.