Secondary Relaxation in glass forming systems

Citation
D. Gomez et al., Secondary Relaxation in glass forming systems, B S ESP CER, 39(3), 2000, pp. 371-373
Citations number
7
Categorie Soggetti
Material Science & Engineering
Journal title
BOLETIN DE LA SOCIEDAD ESPANOLA DE CERAMICA Y VIDRIO
ISSN journal
03663175 → ACNP
Volume
39
Issue
3
Year of publication
2000
Pages
371 - 373
Database
ISI
SICI code
0366-3175(200005/06)39:3<371:SRIGFS>2.0.ZU;2-Y
Abstract
In this work, the beta or secondary relaxation of 15 glass forming systems (13 polymers and 2 low molecular weight liquids) has been analysed by means of Broadband Dielectric Spectroscopy from 10(-2) Hz to 10(7) Hz at tempera tures below and slightly above the glass transition temperature. In further analysis of the experimental results, it has been considered this relaxati on as an thermally activated process with a gaussian distribution of activa tion energies. The results obtained in this way have been compared with rec ent theories that relate this phenomenology with the glass transition one.