A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling

Authors
Kakiuchi, F Matsumoto, M Sonoda, M Fukuyama, T Chatani, N Murai, S Furukawa, N Seki, Y
Citation
F. Kakiuchi et al., A new synthetic route to heteroarylsilanes via ruthenium-catalyzed C-H/SiR3 coupling, CHEM LETT, (7), 2000, pp. 750-751
Citations number
15
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
7
Year of publication
2000
Pages
750 - 751
Database
ISI
SICI code
0366-7022(20000705):7<750:ANSRTH>2.0.ZU;2-1
Abstract
Heteroarylsilanes can be synthesized by the reaction of heteroaromatic comp ounds with triorganovinylsilanes with the aid of a Ru-3(CO)(12)-catalyst. A variety of heteroaromatic compounds can be used in this C-H/SiR3 coupling. The coupling reaction was observed to take place at a position beta to the directing carbonyl group, e.g., ketone, ester, and amide, in the case of h eteroaromatic compounds.