K. Lapsa et al., Temperature study of the elastic properties of glycinium phosphite and deuterated glycinium phosphite crystals by brillouin scattering, FERROELECTR, 239(1-4), 2000, pp. 957-962
Brillouin spectroscopy was used to study the elastic properties of glyciniu
m phosphite (GPI) and deuterated glycinium phosphite (DGPI) crystals. The t
emperature measurements of the hypersonic velocity for acoustic modes propa
gating in various directions have been performed in the temperature range 1
70 K-300 K and 295 K-355 K for GPI and DGPI, respectively. Brillouin study
has confirmed the existence of the order-disorder type ferroelectric phase
transition (P2(1)/a - P2(1)) at 224 K for GPI and 322 K for DGPI. The obtai
ned results are also discussed in terms of the reordering of the hydrogen b
onds in the ferroelectric phase.