Absorption spectra peculiarities at the Jahn-Teller ordering in KDy(MoO4)(2)

Citation
Yi. Zagvozdina et al., Absorption spectra peculiarities at the Jahn-Teller ordering in KDy(MoO4)(2), FERROELECTR, 239(1-4), 2000, pp. 1067-1074
Citations number
14
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
FERROELECTRICS
ISSN journal
00150193 → ACNP
Volume
239
Issue
1-4
Year of publication
2000
Pages
1067 - 1074
Database
ISI
SICI code
0015-0193(2000)239:1-4<1067:ASPATJ>2.0.ZU;2-W
Abstract
The absorption spectra of KDy(MoO4)(2) are studied in the region of the low -temperature phase transition of cooperative Jahn-Teller ordering type. The parameters of the fine structure components of the absorption spectrum man ifest anomalies of different type in the temperature region 20-8K. Possible low-temperature phases accompanied with the doubling of the unit cell of i nitial rhombic phase D-2h(14) are analysed. It is shown that the Jahn-Telle r pseudo-effect occurs in KDy(Moo(4))(2) due to the interaction between the electron states of Dy3+ ions and the strains in the "pre-transition" tempe rature region.