E. Peter et J. Stankowska, The effect of L- and DL-Tryptophan admixtures on dielectric properties of TGS crystals, FERROELECTR, 239(1-4), 2000, pp. 1151-1158
The paper reports the effect of L-Tryptophan (L-Tryp) and DL-Tryptophan (DL
-Tryp) admixtures on dielectric properties of TGS crystals. Temperature mea
surements (100-340 K) of permittivity epsilon and loss tangent tg delta of
the samples were performed for selected frequencies of the measuring field
varied from 1 to 10(4) kHz for LTrypTGS and DLTrypTGS crystals with differe
nt concentrations of organic dopants. For the first time the low-frequency
dielectric dispersion was observed in three temperature regions: 140 to 190
K, 230 to 260 K and near the phase transition as the appearance of addition
al maxima of epsilon and tg delta. With increasing concentration of the dop
ants in the admixtured crystals the values of epsilon(max), and tg delta(ma
x) decreased while bias field E-b increased, and Curie temperature T-c show
ed insignificant changes.