T. Shirakami et al., A new method of determining short-range order parameter in relaxor Pb(Ni1/3Nb2/3)O-3 by magnetic susceptibility measurement, JPN J A P 2, 39(7A), 2000, pp. L678-L680
We synthesized Pb(Ni1/3Nb2/3)O-3 (PNN) and performed selected-area electron
diffraction (SAD) in order to investigate the structure of the B-site arra
y. In addition to the reflection from the basic cell, the SAD pattern of si
ntered PNN corresponds to the reciprocal plane normal to the [0 (1) over ba
r 1] zone axis and showed diffuse scatterings at (1/2 1/2 1/2) positions. W
e also measured the magnetic susceptibility of PNN and discussed the short-
range ordering around Ni2+ ions by analyzing the susceptibility based on a
simple model.