USING SCALARANE SESTERTERPENES TO EXAMINE A SPONGE TAXONOMIC ANOMALY

Citation
M. Jaspars et al., USING SCALARANE SESTERTERPENES TO EXAMINE A SPONGE TAXONOMIC ANOMALY, Journal of natural products, 60(6), 1997, pp. 556-561
Citations number
30
Categorie Soggetti
Chemistry,"Plant Sciences","Pharmacology & Pharmacy","Chemistry Medicinal
Journal title
ISSN journal
01633864
Volume
60
Issue
6
Year of publication
1997
Pages
556 - 561
Database
ISI
SICI code
0163-3864(1997)60:6<556:USSTEA>2.0.ZU;2-Y
Abstract
A parallel study was conducted on two Indo-Pacific foliose sponges, Th e first specimen contains 3-hydroxy-20,22-dimethyl-20-deoxoscalarin (2 ), while the second contains 3-oxo-20,22-dimethyl-20-dioxoscalarin 8 ( 3). The physical properties as well as X-ray results confirming the st ructure and stereochemical features of these compounds are presented f irst. The difficulty we encountered in the taxonomic identification of these species is also discussed, One of our specimens rs identical to material considered by different taxonomists as either Phyllospongia vermicularis or Dysidea vermicularis, The other is identified as Carte riospongia sp. We outline that the parallel chemistry of these two spe cimens suggests that they are closely related taxonomically.