Synthesis, structure, and photochemical reaction of 9,10-dihydro-9-silaanthracene derivatives carrying bulky substituents

Authors
Nishiyama, K Oba, M Takagi, H Fujii, I Hirayama, N",Narisu,"Horiuchi, H Okutsu, T Hiratsuka, H
Citation
K. Nishiyama et al., Synthesis, structure, and photochemical reaction of 9,10-dihydro-9-silaanthracene derivatives carrying bulky substituents, J ORGMET CH, 604(1), 2000, pp. 20-26
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
604
Issue
1
Year of publication
2000
Pages
20 - 26
Database
ISI
SICI code
0022-328X(20000605)604:1<20:SSAPRO>2.0.ZU;2-M
Abstract
Some of 9-aryl-9,10-dihydro-9-silaanthracencs (1) were prepared and the alk ylation of the compounds gave trans-9-aryl-10-alkyl-9,10-dihydro-9-silaanth racenes exclusively. Upon photolysis of a 9-phenyl derivative, 9-phenyl-9-s ilaanthracene was confirmed by spectroscopic analysis. Also, structural stu dies of the dihydro compounds were performed by NMR and X-ray. (C) 2000 Els evier Science S.A. All rights reserved.