The heavy-fermion compound UCu5Sn has been studied by means of neutron powd
er diffraction. This compound exhibits the hexagonal CeNi5Sn-type structure
with space group P6(3)/mmc. We have determined the lattice parameters and
atomic positions at room temperature, using a high-resolution diffractomete
r The neutron diffraction diagrams were also measured at various temperatur
es between 1.4 and 61 K, using an 800-cell position-sensitive diffractomete
r. The observed minimum in the unit-cell volume at temperature of 30 K, bri
ng rather far below the magnetic ordering one (T-C = 53 K), may suggest a c
hange in the strength of the Sf-conduction electron hybridization which pro
bably takes place at low temperatures. It was found that the magnetic phase
transition at Te corresponds to the onset of a ferrimagnetic order. The ma
gnetic structure is characterized by forming the ferromagnetic planes (001)
with the (+ - + -) stacking sequence, where the U moments are oriented par
allel to the hexagonal c-axis. However, the size of the U moments arranged
in the z = 0 plane (M-U1), and formed by the sites 2(a), is substantially l
arger than these arranged in the adjacent z = (1)/(4) plane (M-U2), and for
med by the sites 2(c). At 1.4 K, they are M-U1 = 2. 14(2) mu(B)/atom U and
M-U2 = 0.18(4) mu(B)/atom U. We discuss several mechanisms leading to a red
uction of the magnetic moment at the one site compared to the other one.