ISOBARIC VAPOR-LIQUID-EQUILIBRIA OF 3-METHYL-1-BUTANOL WITH METHANOL AND VINYL-ACETATE AT 101.3-KPA

Authors
RESA JM GONZALEZ C MORADILLO B RUIZ A
Citation
Jm. Resa et al., ISOBARIC VAPOR-LIQUID-EQUILIBRIA OF 3-METHYL-1-BUTANOL WITH METHANOL AND VINYL-ACETATE AT 101.3-KPA, Fluid phase equilibria, 132(1-2), 1997, pp. 205-213
Citations number
15
Categorie Soggetti
Engineering, Chemical","Chemistry Physical
Journal title
Fluid phase equilibria → ACNP
ISSN journal
03783812
Volume
132
Issue
1-2
Year of publication
1997
Pages
205 - 213
Database
ISI
SICI code
0378-3812(1997)132:1-2<205:IVO3WM>2.0.ZU;2-R
Abstract
Isobaric vapor-liquid equilibria were determined at 101.3 kPa for the binary mixtures methanol + 3-methyl-1-butanol and vinyl acetate + 3-me thyl-1-butanol. The two systems exhibit positive deviations from ideal behavior. The experimental data were correlated by the Wilson equatio n and were found to be thermodynamically consistent. The selectivity o f 3-methyl-1-butanol solvent was calculated for both systems. No azeot ropes were found for the systems at 101.3 kPa. (C) 1997 Elsevier Scien ce B.V.