Syn-eruptive degassing of volcanoes may lead to syn-eruptive crystallizatio
n of groundmass phases, We have investigated this process using textural an
d compositional analysis of dome material from Merapi volcano, Central Java
, Indonesia. Samples included dome lavas from the 1986-88, 1992-93, 1994 an
d 1995 effusive periods as well as pyroclastic material deposited by the No
vember 1994 dome collapse. With total crystallinities commonly in excess of
70% (phenocrysts + microlites), the liquids present in Merapi andesites ar
e highly evolved (rhyolitic) at the time of eruption. Feldspar microlites i
n dome rocks consist of plagioclase cores (Ab(63)An(29)Or(8)) surrounded by
alkali feldspar rims (Ab(53)An(5)Or(42)). compositional pairs which are no
t in equilibrium. A change in the phase relations of the ternary feldspar s
ystem caused by degassing best explains the observed transition in feldspar
composition. A small proportion of highly vesicular airfall tephra grains
from the 1994 collapse have less evolved glass compositions than typical do
me material and contain rimless plagioclase microlites, suggesting that the
1994 collapse event incorporated less-degassed, partially liquid magma in
addition to fully solidified dome rock.
As decompression drives volatile exsolution, rates of degassing and resulta
nt microlite crystallization may be governed by magma ascent rate. Microlit
e crystallinity is nearly identical among the 1995 dome samples, an indicat
ion that similar microlite growth conditions (PH2O and temperature) were ac
hieved throughout this extrusive period, However, microlite number density
varied by more than a factor of four in these samples, and generally increa
sed with distance from the vent. Low vent-ward microlite number densities a
nd greater microlite concentrations down-flow probably reflect progressivel
y decreasing rates of undercooling at the time of crystal nucleation during
extrusion of the 1995 dome. Comparison between dome extrusion episodes ind
icates a correlation between lava effusion rate and microlite number densit
y, suggesting that extrusion slowed during 1995, Crystal textures and compo
sitions in the 1992-93 and 1994 domes share the range exhibited by the 1995
dome, suggesting that transitions in crystallization conditions (i.e., rat
es of undercooling determined by effusion rate) are cyclic. (C) 2000 Elsevi
er Science B.V. All rights reserved.